From a ham radio friend:
PhysicsWorld: Extra carbon in the atmosphere may disrupt radio communications
"Higher levels of carbon dioxide (CO2) in the Earth’s atmosphere could harm radio communications by enhancing a disruptive effect in the ionosphere. According to researchers at Kyushu University, Japan, who modelled the effect numerically for the first time, this little-known consequence of climate change could have significant impacts on shortwave radio systems such as those employed in broadcasting, air traffic control and navigation."